It is known that aniline usually reacts as a nitrogen nucleophile steroids, forming nitrogen bonded adducts with trinitrobenzene steroids steroids, (TNB) in the presence of a strong base. However, in acidic solutions, a adducts are formed with bonding between a ring carbon atom of the anilines and the 7 position of DNBF. A value of 2.0 for k(_H)/k(_D), the kinetic isotope effect, indicates that bond formation is largely rate determining in the substitution pathway.
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